Man standing in rain wearing Doppler Jacket

Sustainable Durable Water Repellents

DWR on Fabric

Why do we need Durable Water Repellents?

Even if it employs a waterproof membrane, a garment can become saturated (soaked) when exposed to sustained moisture over time. When this happens it impedes the breathability of the membrane below the shell layer. For non-membrane fabrics, small amounts of rain can easily penetrate the fabric and get you wet.

3 -ayer DWR

Waterproof vs. Water Repellent

Because they sound similar and are methods of keeping you dry, "waterproof" and "water repellent" are often used interchangeably by brands - but there is a key distinction between the two.

• Waterproof: keeping water from going through the fabric

• Water repellent/resistant: keeping water off the fabric

With enough rain, a water repellent fabric will become wet.

Polar vs Non Polar

Oil & water

Oil and water don't mix because water is polar (has a + / - charge, like a magnet) and oil is not. This is the reason early methods of keeping clothes dry were through waxing, or oiling canvas to repel moisture.

Electromagnetic Repulsion

Polarity

Polarized molecules repel or attact each other, due to their electromagnetic charge. This repulsive force is critical to the function of DWRs.

Water Molecule

Repelling through the magnetic charge

You can turbo-charge this effect by taking advantage of the fact that water is slightly electronegative - basically, the Oxygen molecule dominates the water molecule and has a negative charge. When you have two magnets with their North or South poles facing each other, they push themselves apart. This is what happens with Perflourinated (PFC) DWRs - they work by using the Fluorine molecule to push away the Oxygen molecule due to their common negative charge.

Water Droplet Contact Angle

Contact angle

When you push away the water, it causes water to "bead up", by increasing surface tension. The water droplets act like balls and simply roll off the fabric.

C6 DWR

Perfluorinated compounds

Most water repellent garments currently use PFC/PFAS (Perflourinated Carboxylic Acid) DWR. However, there is growing research that indicates PFCs can affect our endocrine / hormonal system. Thus, the industry is now moving away from PFCs, relying more on the principle of Oil & Water to keep fabric dry.

C8 DWR

Persistant PFCs

DWR with 8-carbons (C8-DWR) is more durable than 6-carbon DWR - but it persists in our water supply for much longer as a result.

PFC-Free DWR

PFC-free DWR & sustainability

Over the past 12 months, we've been shifting all of our DWRs to C6 and non-PFC, Silicon-based DWRs, and our recent Mercury Jacket, Momentum Chinos, Doppler Mac and Kinetic Jacket all benefit from this change.